Question

In the above reaction 'A' and 'B' are:

• A.

  

• B.

  

• C.

  

• D.

  

Hint:

Oxidation reactions with \( KMnO_4 \) generally add oxygen to the carbon chain, converting alkyl groups to carboxyl groups.

Answer 1

The Correct Option is C

This question involves identifying the products 'A' and 'B' in the given reactions. Let's break down the reaction steps and identify each product.

Reaction Breakdown:

1. The initial reaction involves the oxidation of a ketone using \text{KMnO}_4. This process typically produces a carboxylic acid. Since the given compound is a cyclic ketone, the major product 'A' is likely a cyclic carboxylic acid.

2. The second reaction sequence involves the Wolff-Kishner reduction, where hydrazine (\text{NH}_2\text{NH}_2) and base (KOH) are used. This process reduces the carbonyl group to a methylene group, eliminating the oxygen.

3. The sequence is followed by an acidic hydrolysis. As the compound after the first step is a carboxylic acid, its complete reduction results in the formation of an alkane.

- The reaction involves the oxidation of the allyl group to a carboxylic acid group (\(COOH\)) via \( KMnO_4 \).
- The second step involves a nucleophilic substitution reaction with \( NH_3 \) and \( NaOH \), forming the amine group (\( NH_2 \)).
Thus, the final product is a compound with both \( COOH \) and \( NH_2 \) groups.