Baeyer's reagent, a cold, dilute, alkaline potassium permanganate (KMnO4) solution, serves as a potent oxidizing agent for detecting unsaturation (double or triple bonds) in organic compounds. The permanganate ion (MnO4-) exhibits a deep purple hue. Upon reaction with unsaturated compounds, this purple color dissipates, yielding a brown precipitate of manganese dioxide (MnO2). The disappearance of the permanganate's color signifies a positive test for unsaturation. Maintaining a cold and dilute solution is crucial to prevent overly vigorous reactions that could lead to further oxidation of the organic compound.
The correct order of the rate of reaction of the following reactants with nucleophile by \( \mathrm{S_N1} \) mechanism is:
(Given: Structures I and II are rigid) 