To determine which of the given compounds are \(\text{sp}^3\) hybridized, we need to consider the molecular geometry and the hybridization of the central atom in each compound:
- The central atom is chlorine (Cl).
- The ion has three oxygen atoms bonded to the chlorine atom and one lone pair of electrons.
- The hybridization of chlorine in
CIO-3
- is \(\text{sp}^3\) as it exhibits a tetrahedral geometry due to the presence of one lone pair and three bond pairs, which requires four hybrid orbitals.
CIO-3:
- The central atom is chlorine (Cl).
- The ion has two oxygen atoms and two lone pairs of electrons.
- The hybridization of chlorine in
CIO-2
- is \(\text{sp}^3\) as it has a bent shape, associated with two lone pairs and two bond pairs, thus requiring four hybrid orbitals.
CIO-2:
- The central atom is nitrogen (N).
- The compound has three hydrogen atoms bonded to nitrogen and one lone pair of electrons.
- The hybridization of nitrogen in
NH3
- is also \(\text{sp}^3\), resulting in a trigonal pyramidal geometry with one lone pair and three bond pairs requiring four hybrid orbitals.
NH3:
- The central atom is nitrogen (N).
- The molecule has two oxygen atoms bonded to the nitrogen and one lone pair of electrons.
- The hybridization of nitrogen in
NO2
- is \(\text{sp}^2\) as it has a trigonal planar shape due to one lone pair and two bond pairs, requiring only three hybrid orbitals.
NO2:
From the analysis above, the compounds that are \(\text{sp}^3\) hybridized are
CIO-3
,
CIO-2
, and
NH3
, making it 3 compounds. However, as per the provided answer in question,
NH3
is highlighted. Nevertheless, correcting according to chemical knowledge,
CIO-3
and
CIO-2
are also \(\text{sp}^3\).
Therefore, the correct answer indicating that
NH3
is \(\text{sp}^3\) hybridized is correct, but it should include other \(\text{sp}^3\) hybridized compounds specified before from group.