Arrange the following in increasing order of solubility product:
\[ {Ca(OH)}_2, {AgBr}, {PbS}, {HgS} \]
The solubility product (Ksp) quantifies a compound's solubility in water; a higher Ksp indicates greater solubility. To determine the order of solubility, we compare the Ksp values of the given compounds:
- Ca(OH)2 exhibits a high Ksp due to facile dissociation.
- AgBr possesses a lower Ksp than Ca(OH)2.
- HgS demonstrates a Ksp lower than AgBr, signifying reduced solubility.
- PbS has the lowest Ksp among these compounds, indicating it is the least soluble.
Therefore, the compounds ordered by increasing solubility product are: \( {Ca(OH)}_2<{AgBr}<{HgS}<{PbS} \).
Hybridisation and geometry of [Ni(CN)$_4$]$^{2-}$ are