Question:hard

' $A$' and ' $B$ ' formed in the following set of reactions are:
 A' and ' B ' formed in the following set of reactions are:

Updated On: Mar 30, 2026
  •  A' and ' B ' formed in the following set of reactions are:\

  •  A' and ' B ' formed in the following set of reactions are:

  •  A' and ' B ' formed in the following set of reactions are:

  •  A' and ' B ' formed in the following set of reactions are:

Show Solution

The Correct Option is A

Solution and Explanation

The given set of reactions involves the conversion of alcohols to bromoalkanes using HBr under heat. The reactions are as follows:

  1. The first reaction is the conversion of benzyl alcohol (\(\text{C}_6\text{H}_5\text{CH}_2\text{OH}\)) to benzyl bromide (\(\text{C}_6\text{H}_5\text{CH}_2\text{Br}\)). In the presence of HBr and heat, the hydroxyl group (-OH) is replaced by a bromine atom to form compound A.
  2. The second reaction involves the conversion of p-methoxyphenol to 4-bromoanisole. The presence of the methoxy group (-OCH3) directs the bromination to the para position of the aromatic ring, leading to the formation of compound B.

In both reactions, the hydroxyl group is substituted by a bromine atom in the presence of HBr and elevated temperature.

Therefore, the correct identification of the compounds A and B formed in the reactions is as follows:

In summary, compound A is benzyl bromide, and compound B is 4-bromoanisole, consistent with the provided reactions and the correct answer.

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