Question:medium

The spin-only magnetic moment (\(\mu\)) value (B.M.) of the compound with the strongest oxidising power among \(Mn_2O_3\), \(TiO\), and \(VO\) is ________________________ B.M. (Nearest integer).

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For transition metals, the higher the oxidation state, the stronger the oxidising power.
Updated On: Jan 14, 2026
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Correct Answer: 4

Solution and Explanation

The magnetic moment (\(\mu\)) is calculated using the formula: \[ \mu = \sqrt{n(n+2)} \, \text{B.M.} \] Here, \( n \) represents the number of unpaired electrons.

  • For \( Mn_2O_3 \): The manganese (Mn) has a \( +3 \) oxidation state, corresponding to a \( d^4 \) configuration with 4 unpaired electrons.
  • For \( TiO \): The titanium (Ti) has a \( +2 \) oxidation state, corresponding to a \( d^2 \) configuration with 2 unpaired electrons.
  • For \( VO \): The vanadium (V) has a \( +2 \) oxidation state, corresponding to a \( d^3 \) configuration with 3 unpaired electrons.

Given that \( Mn_2O_3 \) exhibits the highest oxidation state and the strongest oxidizing power, its magnetic moment is computed as follows: \[ \mu = \sqrt{4(4+2)} = \sqrt{24} \approx 4.9 \] Rounded to the nearest whole number, the magnetic moment is 4 B.M.

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