The spin-only magnetic moment (\(\mu\)) value (B.M.) of the compound with the strongest oxidising power among \(Mn_2O_3\), \(TiO\), and \(VO\) is ……. B.M. (Nearest integer).
The magnetic moment (\(\mu\)) is calculated using the formula: \[ \mu = \sqrt{n(n+2)} { B.M.} \] where \( n \) represents the number of unpaired electrons.
- \( Mn_2O_3 \): Manganese is in the \( +3 \) oxidation state (\(d^4\)), resulting in 4 unpaired electrons.
- \( TiO \): Titanium is in the \( +2 \) oxidation state (\(d^2\)), resulting in 2 unpaired electrons.
- \( VO \): Vanadium is in the \( +2 \) oxidation state (\(d^3\)), resulting in 3 unpaired electrons.
Considering \( Mn_2O_3 \) exhibits the highest oxidation state and strongest oxidizing capacity, its magnetic moment is calculated as: \[ \mu = \sqrt{4(4+2)} = \sqrt{24} \approx 4.9 \] Rounded to the nearest integer, the magnetic moment is 4 B.M.
(b) If \( \vec{L} \) is the angular momentum of the electron, show that:
\[ \vec{\mu} = -\frac{e}{2m} \vec{L} \]