The addition of Fe2O3, being a solid, will not affect the equilibrium since its concentration is not included in the equilibrium constant expression. Conversely, altering the concentration of CO2, either by addition or removal, will cause a shift in equilibrium in accordance with Le-Chatelier’s principle. Similarly, the removal of CO will disturb the equilibrium by shifting it towards the reactants.
Therefore, the correct choice is Option (1).
At a given temperature and pressure, the equilibrium constant values for the equilibria are given below:
$ 3A_2 + B_2 \rightleftharpoons 2A_3B, \, K_1 $
$ A_3B \rightleftharpoons \frac{3}{2}A_2 + \frac{1}{2}B_2, \, K_2 $
The relation between $ K_1 $ and $ K_2 $ is: