Given Information:
Step 1: Determine Moles Change
Let \( x \) represent the moles of \(\mathrm{N_2}\) reacted. Stoichiometry dictates the changes:
| \(\mathrm{N_2}\) | \(\mathrm{H_2}\) | \(\mathrm{NH_3}\) | |
| Initial (moles) | 1 | 3 | 0 |
| Change (moles) | -x | -3x | +2x |
| Equilibrium (moles) | 1-x | 3-3x | 2x |
Step 2: Calculate \( x \)
At equilibrium, \(\mathrm{NH_3}\) is 0.4 moles:
\[ 2x = 0.4 \implies x = 0.2 \text{ moles} \]
Step 3: Calculate Equilibrium Moles of \(\mathrm{H_2}\)
Substitute \( x = 0.2 \) into the \(\mathrm{H_2}\) equilibrium expression:
\[ \text{Moles of } \mathrm{H_2} = 3 - 3x = 3 - 3(0.2) = 3 - 0.6 = 2.4 \text{ moles} \]
Step 4: Verification of Equilibrium Moles
Conclusion
The equilibrium concentration of \(\mathrm{H_2}\) is \(\boxed{2.4 \text{ moles}}\).
Final Answer
The calculated equilibrium concentration of \(\mathrm{H_2}\) is:
\[ \boxed{2.4 \text{ moles}} \]
Consider the following gas phase dissociation, PCl$_5$(g) $\rightleftharpoons$ PCl$_3$(g) + Cl$_2$(g) with equilibrium constant K$_p$ at a particular temperature and at pressure P. The degree of dissociation ($\alpha$) for PCl$_5$(g) is
PCl$_5$(g) $\rightleftharpoons$ PCl$_3$(g) + Cl$_2$(g)
For the reaction A(g) $\rightleftharpoons$ 2B(g), the backward reaction rate constant is higher than the forward reaction rate constant by a factor of 2500, at 1000 K.
[Given: R = 0.0831 atm $mol^{–1} K^{–1}$]
$K_p$ for the reaction at 1000 K is: