The condition for an electron's de-Broglie wavelength in an orbit is stated as:
\[ 2 \pi r_n = n \lambda_d \]
Here, \( r_n \) denotes the radius of the \( n \)-th orbit, \( n \) is the principal quantum number, and \( \lambda_d \) represents the de-Broglie wavelength.
The radius of the \( n \)-th orbit within the Bohr model is defined by:
\[ r_n = 2 \pi a_0 \frac{n^2}{Z} \]
Substituting this expression yields:
\[ 2 \pi a_0 \frac{n^2}{Z} = n \lambda_d \]
For an electron occupying the 4th orbit of a hydrogen atom (\( Z = 1 \)):
\[ 2 \pi a_0 \frac{4^2}{1} = 4 \lambda_d \]
Upon simplification:
\[ \lambda_d = 8 \pi a_0 \]
Therefore, the de-Broglie wavelength of the electron in the 4th orbit is determined to be \( 8 \pi a_0 \).