Benzene, molecular formula C\(_6\)H\(_6\), is a recognized aromatic compound. Its structure is a planar ring of carbon atoms with delocalized pi electrons due to alternating single and double bonds, creating a conjugated system.
Each carbon-carbon double bond contributes 2 \( \pi \)-electrons. With 6 carbon atoms involved in conjugation, the total count of \( \pi \)-electrons in benzene is 6.
Therefore, the result is:
\[\text{The number of } \pi \text{ electrons} = 6\]