The spin-only magnetic moment is calculated using the formula \[\mu = \sqrt{n(n+2)} \, \text{B.M.}\], where \(n\) represents the number of unpaired electrons. For \( Fe^{3+} \) in \( K_3[Fe(OH)_6] \) and \( Fe^{2+} \) in \( K_4[Fe(OH)_6] \), the number of unpaired electrons are determined from their electronic configurations. \( Fe^{3+} \) has 5 unpaired electrons, yielding a magnetic moment of 5.92 B.M., while \( Fe^{2+} \) has 4 unpaired electrons, resulting in a magnetic moment of 4.90 B.M.