The angle between vector \( (\vec{A}) \) and \( (\vec{A} - \vec{B}) \) is: 
To find the angle between the vectors (\vec{A}) and (\vec{A} - \vec{B}), we use the dot product formula:
\vec{A} \cdot (\vec{A} - \vec{B}) = |\vec{A}||\vec{A} - \vec{B}|\cos \theta
Given the vectors, this expands to:
\vec{A} \cdot \vec{A} - \vec{A} \cdot \vec{B} = |\vec{A}||\vec{A} - \vec{B}|\cos \theta
Hence,
A^2 - AB \cos \theta' = A \sqrt{A^2 + B^2 - 2AB \cos \theta'} \cos \theta
Given that the angle \theta' is 120° as seen in the diagram:
\cos 120^\circ = -\frac{1}{2}
Substitute \cos 120^\circ in the equation:
A^2 + \frac{AB}{2} = A \sqrt{A^2 + B^2 + AB} \cos \theta
Rearrange and solve for \cos \theta:
\cos \theta = \frac{A^2 + \frac{AB}{2}}{A \sqrt{A^2 + B^2 + AB}}
Using the identity \tan \theta = \frac{\sin \theta}{\cos \theta}, calculate \tan \theta as follows:
\tan \theta = \frac{\sqrt{3} B}{2A - B}
The option that matches this result is:
(B) \tan^{-1} \left( \frac{\sqrt{3} B}{2A - B} \right)

The correct answer is, therefore, option (B).