To determine the largest natural number \(n\) for which \(3^n\) divides \(66!\), we need to find the highest power of 3 that divides \(66!\). This can be calculated using the formula for finding powers of a prime \(p\) in \(n!\):
\[\sum_{k=1}^{\infty} \left\lfloor \frac{66}{3^k} \right\rfloor\]
For \(p=3\) and \(n=66\), calculate each term until the floor function results in zero:
Since subsequent terms are zero, we stop here. Summing these values gives:
\[22 + 7 + 2 = 31\]
Thus, the largest \(n\) such that \(3^n\) divides \(66!\) is 31.
Confirming against the provided range, \(31\) is indeed within the expected range of \([31, 31]\).