Question:medium

Among the following pentachlorides, which one does not exist due to the inert pair effect?

Show Hint

Think about which group 15 element shows the strongest inert pair effect.
Updated On: Jul 3, 2026
  • PCl5
  • BiCl5
  • SbCl5
  • AsCl5
Show Solution

The Correct Option is B

Solution and Explanation

BiF5 exists (F stabilizes +5 via strong bonds), but Bi-Cl bonds are too weak, and Bi(V) oxidizes Cl- to Cl2, leaving BiCl3.
\[\boxed{BiCl_5}\]
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