Question:medium

How many P–O–Plinkages are there in P4O10?

Updated On: Jan 29, 2026
  • Six
  • Four
  • Five
  • One
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The Correct Option is A

Solution and Explanation

\(P_4O_{10}\), also known as tetraphosphorus decaoxide, has the empirical formula for phosphorus pentoxide. Its structure features four phosphorus atoms in a tetrahedral arrangement. Each phosphorus atom bonds to one terminal oxygen atom (\(P=O\)) and three bridging oxygen atoms, creating \(P-O-P\) linkages.

To find the number of \(P-O-P\) linkages:

* Each phosphorus atom connects to three bridging oxygen atoms. * Each bridging oxygen atom links two phosphorus atoms.

Consequently, the \(P_4O_{10}\) molecule contains a total of 6 \(P-O-P\) linkages. Picture the four phosphorus atoms as a tetrahedron. Each edge of the tetrahedron represents a bridging oxygen atom, thus creating six P-O-P linkages, mirroring the tetrahedron's six edges.

Structure Visualization:

Each P atom is tetrahedrally coordinated. There are four terminal oxygen atoms double bonded to the four P atoms. The remaining six oxygen atoms bridge between the P atoms.

In summary, \(P_4O_{10}\) has six \(P-O-P\) linkages.

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