A buffer solution contains 100ml of 0.01(M) \(\text{CH}_3\text{COOH}\) and 200ml of 0.02(M) \(\text{CH}_3\text{COONa}\). 700ml of water is added subsequently to the buffer solution. The pH before and after dilution are [given, \(\text{p}K_a = 4.74\); \(\log 2 = 0.301\)]