Question:medium

Equal volumes of aqueous solution of 0.1 M HCl and 0.2 M H2SO4 are mixed. The concentration of H+ ions in the resulting solution is:

Updated On: Jan 29, 2026
  • 0.15 M
  • 0.30 M
  • 0.10 M
  • 0.25 M
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The Correct Option is D

Solution and Explanation

  • Hydrochloric acid (HCl) is monoprotic; thus, a 0.1 M solution yields 0.1 M H+ ions.
  • Sulfuric acid (H2SO4) is diprotic; therefore, a 0.2 M solution provides 2 × 0.2 = 0.4 M H+ ions.

Upon mixing equal volumes, the total volume doubles, halving each acid's concentration:

New HCl concentration = \(\frac{0.1}{2} = 0.05 \text{M H}^+\)

New H2SO4 concentration = \(\frac{0.4}{2} = 0.2 \text{M H}^+\)

The combined H+ concentration is:

\( 0.05 \text{M} + 0.2 \text{M} = 0.25 \text{M} \)

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