Question:medium

X ⇌ Y;K1 = 1
Y ⇌ Z; K2 = 2
Z ⇌ W; K3 = 4
Find Keq for X ⇌ W

Updated On: Mar 25, 2026
  • 12
  • 8
  • 2
  • 4
Show Solution

The Correct Option is B

Solution and Explanation

To find the equilibrium constant \( K_{\text{eq}} \) for the reaction \( X \leftrightarrow W \), we need to use the relationship between the given reactions and their equilibrium constants. The given reactions and their equilibrium constants are:

  1. \( X \leftrightarrow Y \) with \( K_1 = 1 \)
  2. \( Y \leftrightarrow Z \) with \( K_2 = 2 \)
  3. \( Z \leftrightarrow W \) with \( K_3 = 4 \)

The overall reaction for \( X \leftrightarrow W \) can be obtained by summing up the individual reactions:

  1. X \leftrightarrow Y
  2. Y \leftrightarrow Z
  3. Z \leftrightarrow W

When combining these reactions, intermediate species (\( Y \) and \( Z \)) will cancel out, yielding:

  1. X \leftrightarrow W

The equilibrium constant for the overall reaction is the product of the individual equilibrium constants:

K_{\text{eq}} = K_1 \times K_2 \times K_3

Substituting the given values:

K_{\text{eq}} = 1 \times 2 \times 4 = 8

Therefore, the equilibrium constant for the reaction \( X \leftrightarrow W \) is 8.

Thus, the correct answer is 8.

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