The question is about identifying the oxoacid of phosphorus that contains the highest number of oxygen atoms in its chemical formula. To solve this, we need to consider the chemical formulas of each given option:
Analyzing the number of oxygen atoms in each formula, Pyrophosphoric acid with the formula H_4P_2O_7 contains the highest number of oxygen atoms (7 oxygen atoms).
Thus, the correct answer is Pyrophosphoric acid which contains 7 oxygen atoms, the most among the given options.