Question:hard

Which of the following vanadium pentahalides exists?

Show Hint

Only fluoride is small and resistant enough to redox to form a stable pentahalide with V(V).
Updated On: Jul 3, 2026
  • VF5
  • VCl5
  • VBr5
  • VI5
Show Solution

The Correct Option is A

Solution and Explanation

Small V5+ (0.54 A) can only pack 5 small F- ions around it without steric strain; larger halides can't pack and also get oxidized.
\[\boxed{VF_5}\]
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