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d and f Block Elements
which of the following va...
Question:
hard
Which of the following vanadium pentahalides exists?
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Only fluoride is small and resistant enough to redox to form a stable pentahalide with V(V).
CPET - 2025
CPET
Updated On:
Jul 3, 2026
VF5
VCl5
VBr5
VI5
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The Correct Option is
A
Solution and Explanation
Small V5+ (0.54 A) can only pack 5 small F- ions around it without steric strain; larger halides can't pack and also get oxidized.
\[\boxed{VF_5}\]
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