Question:medium

Which of the following statements is correct?

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Bromine water oxidizes aldehydes but does not oxidize ketones under ordinary conditions.
Updated On: May 20, 2026
  • Glucose is a ketose sugar.
  • Glucose does not reduce Tollens' reagent.
  • Glucose is oxidized to gluconic acid by \(Br_2(aq)\).
  • Glucose gives negative Fehling test.
Show Solution

The Correct Option is C

Solution and Explanation

Understanding the Concept: Glucose is an aldohexose and contains an aldehyde functional group in its open-chain structure.
Step 1: Nature of glucose. Glucose contains six carbon atoms and one aldehyde group. Therefore, it is an aldose sugar, not a ketose sugar.
Step 2: Oxidation with bromine water. Bromine water is a mild oxidizing agent. It oxidizes aldehyde groups into carboxylic acids. Thus, glucose is oxidized to gluconic acid: \[ \mathrm{Glucose \xrightarrow{Br_2(aq)} Gluconic\ acid} \]
Step 3: Reducing nature of glucose. Because glucose contains an aldehyde group, it reduces: \[ \text{Tollens' reagent} \] and \[ \text{Fehling solution} \] Therefore, statements (2) and (4) are incorrect.
Step 4: Conclusion. Hence, option (3) is correct.
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