Let's analyze the given options based on the atomic number 79, which corresponds to the element Gold (Au). Gold is situated in Group 11 of the periodic table.
- Its first ionisation enthalpy is maximum in its group: This statement is correct. Gold (Au), being a noble metal, has a high ionization enthalpy compared to other elements in the same group (Group 11: Copper (Cu), Silver (Ag), and Gold (Au)). This is because as we move down the group, the atomic size increases, but Gold has particularly strong relativistic and d-orbital effects that increase its ionization energy.
- Its first ionisation enthalpy is minimum in its group: This statement is incorrect. As explained above, Gold has the highest first ionization enthalpy in Group 11.
- It belongs to group 10 of the periodic table: This statement is incorrect. Gold is in Group 11, not Group 10. Group 10 contains elements like Nickel (Ni), Palladium (Pd), and Platinum (Pt).
- It belongs to 5th period of the periodic table: This statement is incorrect. Gold is located in the 6th period of the periodic table.
Therefore, the correct statement regarding an element with atomic number 79 is: "Its first ionisation enthalpy is maximum in its group."