Question:easy

Which lanthanoid from following exhibits \(f^{14}\) configuration in +3 state?

Show Hint

Lanthanoid 4f runs from f0 (La) to f14 (Lu). In +3 state, Lu3+ has 4f14.
Updated On: Oct 1, 2026
  • Tm
  • Lu
  • Ce
  • Dy
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Count from lanthanum:
$\text{La}^{3+}$ is $4f^0$ (Z = 57). Each next element adds one 4f electron in the +3 state.

Step 2: Place the options:
Ce (58): $f^1$. Dy (66): $f^9$. Tm (69): $f^{12}$. Lu (71): $f^{14}$.

Step 3: Conclusion:
The 4f subshell holds at most 14 electrons, and the last element Lu completes it. So Lu is the one.

Step 4: Link to the lanthanoid contraction:
Across the series each added electron goes into the inner 4f subshell. That is why the +3 ions get steadily smaller, and why Lu3+ with a full 4f subshell is the smallest and most stable. The cerium, dysprosium and thulium ions have partly filled 4f subshells, so they cannot show f14.

Final Answer:
Option (B), lutetium. \[ \boxed{\text{Lu (B)}} \]
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