The photoelectric effect equation, \(E_k = h(f - f_0)\), is employed to determine the threshold wavelength of a metal surface exposed to light. This equation links the kinetic energy of emitted electrons (\(E_k\)) to the incident light's frequency (\(f\)) and the material's work function (\(hf_0\)).
The kinetic energy of ejected electrons is further defined by \(E_k = eV_s\), where \(V_s\) is the stopping potential and \(e\) is the elementary charge.
The relationship between light's frequency and wavelength is given by \(f = \frac{c}{\lambda}\), where \(c\) is the speed of light.
Substituting \(f = \frac{c}{\lambda}\) into the photoelectric equation yields \(E_k = h\frac{c}{\lambda} - hf_0\). With \(E_k = eV_s\), this becomes \(eV_s = h\frac{c}{\lambda} - hf_0\).
We consider two scenarios with different stopping potentials:
Rearranging these equations to solve for \(hf_0\):
From scenario 1: \(hf_0 = h\frac{c}{\lambda} - 8e\)
From scenario 2: \(hf_0 = h\frac{c}{3\lambda} - 2e\)
Equating the expressions for \(hf_0\):
\(h\frac{c}{\lambda} - 8e = h\frac{c}{3\lambda} - 2e\)
Isolating terms involving \(h\frac{c}{\lambda}\) and constants:
\(h\frac{c}{\lambda} - h\frac{c}{3\lambda} = 8e - 2e\)
\(h c \left( \frac{1}{\lambda} - \frac{1}{3\lambda} \right) = 6e\)
Simplifying the expression in the parenthesis:
\(h c \left( \frac{2}{3\lambda} \right) = 6e\)
Solving for \(h\frac{c}{\lambda}\):
\(h\frac{c}{\lambda} = 9e\)
Now, substitute this back into the rearranged equation from scenario 1 to find \(hf_0\):
\(hf_0 = 9e - 8e = e\)
The threshold frequency \(f_0\) is related to the threshold wavelength \(\lambda_0\) by \(f_0 = \frac{c}{\lambda_0}\). Therefore, \(hf_0 = h\frac{c}{\lambda_0}\).
Setting \(h\frac{c}{\lambda_0}\) equal to \(e\):
\(h\frac{c}{\lambda_0} = e\)
We also know from the simplified equation \(h\frac{c}{\lambda} = 9e\). We can express \(h\frac{c}{\lambda_0}\) in terms of this:
\(\frac{h\frac{c}{\lambda_0}}{h\frac{c}{\lambda}} = \frac{e}{9e}\)
\(\frac{\lambda}{\lambda_0} = \frac{1}{9}\)
\(\lambda_0 = 9\lambda\)
The threshold wavelength \(\lambda_0\) is found to be \(9\lambda\).