Step 1: Underlying Concept:
For collision: relative velocity must be along the line joining the two particles, i.e., along relative displacement.
Step 2: Explanation:
At time \(t\): \(\mathbf{r}_1 + \mathbf{v}_1 t = \mathbf{r}_2 + \mathbf{v}_2 t\). Rearranging: \(\mathbf{r}_1 - \mathbf{r}_2 = (\mathbf{v}_2 - \mathbf{v}_1)t\). So displacement vector \((\mathbf{r}_1 - \mathbf{r}_2)\) must be parallel to relative velocity \((\mathbf{v}_2 - \mathbf{v}_1)\). This gives the unit vector condition (option A).
Step 3: Conclusion:
\[
\boxed{\dfrac{\mathbf{r}_1 - \mathbf{r}_2}{|\mathbf{r}_1 - \mathbf{r}_2|} = \dfrac{\mathbf{v}_2 - \mathbf{v}_1}{|\mathbf{v}_2 - \mathbf{v}_1|}}
\]