Question:medium

The wrong statement regarding Galvanic cell is

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Remember L-A-N: Left, Anode, Negative (for Galvanic cells).
  • In this spontaneous redox reaction occurs
  • Salt bridge maintains electrical neutrality between the two solutions
  • Anode is represented by (+) and cathode by (-)
  • At anode oxidation occurs
Show Solution

The Correct Option is C

Solution and Explanation

Step 1: Understanding the Concept:
A Galvanic (or Voltaic) cell converts chemical energy into electrical energy through a spontaneous redox reaction. It is important to distinguish its electrode polarity from an electrolytic cell.
Step 2: Key Formula or Approach:
Use the mnemonic LOAN: Left Oxidation Anode Negative.
Step 3: Detailed Explanation:

Statement 1: Correct. Galvanic cells run on spontaneous reactions ($\Delta G<0$).
Statement 2: Correct. The salt bridge completes the circuit and prevents charge build-up by allowing ion flow.
Statement 3: Incorrect. In a Galvanic cell, the Anode is Negative (-) and the Cathode is Positive (+). This is because the anode is the source of electrons.
Statement 4: Correct. Oxidation always occurs at the anode, regardless of the cell type.
Step 4: Final Answer:
Statement (3) is wrong.
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