Question:medium

The UV-visible absorption bands in the spectra of lanthanoid ions are ‘X’, probably because of the excitation of electrons involving ‘Y’. The ‘X’ and ‘Y’, respectively, are :

Updated On: Jan 13, 2026
  • Broad and f orbitals
  • Narrow and f orbitals
  • Broad and d and f orbitals
  • Narrow and d and f orbitals
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The Correct Option is B

Solution and Explanation

Lanthanides exhibit narrow absorption bands in the UV-visible spectrum. This phenomenon occurs because the outer electrons effectively shield the f orbitals. Consequently, electronic transitions within the \(f\) orbitals are minimally influenced by external factors such as ligands or other ions. This shielding results in the characteristic narrow and distinct absorption bands, which arise from transitions involving \(f\) orbitals.
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