To determine the set of all real numbers \alpha for which the expression w = \frac{1 + (1 - 8\alpha)z}{1 - z} is purely imaginary for all z \neq 1, we need to look at the real and imaginary parts of w and set the real part to zero.
Thus the set of \alpha for which w is purely imaginary for all permissible z is \{ 0 \}.