The ratio of \( N_2 \) and \( O_2 \) gases in the atmosphere is \( 4:1 \). The ratio of the mole fractions of the dissolved gases \( N_2:O_2 \) in rain water will be approximately --------. At \( 293\,K \), \( K_H \) for Nitrogen and Oxygen in kbar units are \( 76.48 \) and \( 34.86 \) respectively.