Question:medium

The product A formed in the following reaction is:
 reaction

Updated On: Mar 25, 2026
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Show Solution

The Correct Option is C

Solution and Explanation

To determine product "A", we must analyze the reaction shown. This reaction transforms an aromatic amine into its diazonium salt, followed by a Sandmeyer reaction.

  1. The initial compound is aniline, \(\text{C}_6\text{H}_5\text{NH}_2\).
  2. Reacting aniline with \(\text{NaNO}_2\) and \(\text{HCl}\) at \(0^\circ\text{C}\) produces the diazonium salt, \(\text{C}_6\text{H}_5\text{N}_2^+\text{Cl}^−\).
  3. In the subsequent Sandmeyer reaction step, this diazonium salt reacts with \(\text{Cu}_2\text{Cl}_2\), substituting the diazonium group with a chlorine atom.

This substitution of the diazonium group with chlorine yields chlorobenzene, \(\text{C}_6\text{H}_5\text{Cl}\).

Therefore, chlorobenzene is the resulting product "A". The option representing chlorobenzene is displayed below:

Conclusion: Chlorobenzene is product "A" of this reaction, as indicated by the correct option presented above.

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