Step 1: Pair up opposite corners:
Opposite equal charges give zero net field at $O$ when they have the same sign: (A, D) and (C, F) both cancel.
Step 2: Compare the remaining charges:
What remains of the five is the single charge B $= -q$, giving a field $E_B = \frac{kq}{r^2}$ along $OB$. The sixth charge E gives $E_E = \frac{kQ}{r^2}$, also along $OB$.
Since $E_B = 3E_E$, we get $q = 3Q$, so $Q = \frac q3$.
Final Answer:
$Q = \frac{q}{3}$, option (A).
\[ \boxed{\frac{q}{3}} \]