Gauss's law, \( \oint \vec{E} \cdot d\vec{A} = \frac{Q}{\varepsilon_0} \), is used to determine the electric field. Here, \( Q \) represents the total enclosed charge, and \( \varepsilon_0 \) is the vacuum permittivity.
Step 1: Relate charge to surface density. The total charge \( Q \) on a spherical shell is calculated using the surface charge density \( \sigma \) and the shell's surface area, \( 4\pi R^2 \): \[ Q = \sigma \cdot 4\pi R^2. \]
Step 2: Simplify the electric field calculation. Due to symmetry, the electric field at the spherical shell's surface is uniform. The flux through a spherical Gaussian surface of radius \( R \) is given by: \[ \oint \vec{E} \cdot d\vec{A} = E \cdot 4\pi R^2, \] where \( E \) is the electric field's magnitude. Substituting this into Gauss's law yields: \[ E \cdot 4\pi R^2 = \frac{Q}{\varepsilon_0}. \] Replacing \( Q \) with its expression: \[ E \cdot 4\pi R^2 = \frac{\sigma \cdot 4\pi R^2}{\varepsilon_0}. \] By canceling \( 4\pi R^2 \) from both sides: \[ E = \frac{\sigma}{\varepsilon_0}. \]
Final Answer: \[ \boxed{\frac{\sigma}{\varepsilon_0}}. \]