To solve this problem, we need to understand the relationship between the number of air molecules and their collision frequency. Collision frequency is directly proportional to the number of molecules in a given volume.
The collision frequency, \( Z \), can be expressed by the formula:
Z \propto n
where \( n \) is the number of molecules per unit volume.
Let's denote:
The collision frequency ratio \( \frac{Z_1}{Z_2} \) can be found using the ratio of the number of molecules:
\frac{Z_1}{Z_2} = \frac{n_1}{n_2}
Substituting the given values:
\frac{Z_1}{Z_2} = \frac{3 \times 10^{19}}{12 \times 10^{19}}
On simplification:
\frac{Z_1}{Z_2} = \frac{3}{12} = \frac{1}{4} = 0.25
Thus, the ratio of the collision frequency of air molecules before and after the increase is 0.25.
Conclusion: The correct answer is 0.25.