To solve this problem, we need to determine the amount of methane (CH4) required to produce 81 g of water (H2O) through complete combustion.
The balanced chemical equation for the complete combustion of methane is:
CH4 + 2O2 → CO2 + 2H2O
From the equation, we see that 1 mole of CH4 produces 2 moles of H2O.
First, calculate the moles of water produced. The molar mass of H2O is approximately 18 g/mol.
Moles of H2O = 81 g / 18 g/mol = 4.5 mol
According to the stoichiometry of the reaction, 2 moles of H2O are produced from 1 mole of CH4. Thus, the moles of CH4 needed are:
4.5 mol H2O × (1 mol CH4 / 2 mol H2O) = 2.25 mol CH4
The result, 2.25 mol, can be expressed as 225 × 10–2 mol when multiplied by 102.
Verification within the range: The computed value is clearly falling within the range provided, as it corresponds to 225 in a format of × 10–2 mol.
Therefore, the answer is 225 × 10–2 mol.