Step 1: Recall the elementary transform $\mathcal{L}\{1\}=\dfrac{1}{s}$ for $s>0$, obtained directly from $\int_0^\infty e^{-st}\,dt=1/s$.
Step 2: Invoke the first shifting (frequency-shift) theorem: if $\mathcal{L}\{g(t)\}=G(s)$, then
\[ \mathcal{L}\{e^{-at}g(t)\} = G(s+a). \]
Step 3: Take $g(t)=1$ so that $G(s)=\dfrac{1}{s}$.
Step 4: Replace $s$ by $s+a$ in $G(s)$:
\[ \mathcal{L}\{e^{-at}\cdot 1\} = G(s+a) = \frac{1}{s+a}. \]
Step 5: This matches the direct integration, so the transform of $e^{-at}$ is $\dfrac{1}{s+a}$, converging for $\operatorname{Re}(s)>-a$.
\[ \boxed{\, \mathcal{L}\{e^{-at}\} = \dfrac{1}{s+a} \,} \]