Question:medium

The highest oxidation state of manganese in fluoride is +4 (MnF\(_4\)), but the highest oxidation state in oxides is +7 (Mn\(_2\)O\(_7\)), because

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When comparing the ability of oxygen and fluorine to stabilize high oxidation states of transition metals, remember that oxygen's ability to form multiple (double) bonds often outweighs fluorine's higher electronegativity. This is a common trend for many transition metals.
Updated On: Apr 28, 2026
  • Fluorine is more electronegative than oxygen
  • Fluorine possesses d-orbitals
  • Fluorine stabilises lower oxidation state
  • In covalent compounds, fluorine can form single bond only, while oxygen forms double bond
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Concept:
The ability of an element to exhibit a high oxidation state depends heavily on the bonding characteristics of the electronegative atoms it coordinates with.
Step 2: Key Formula or Approach:
Analyze the valency and bonding capabilities (single vs. multiple bonds) and the resulting steric crowding effects of fluorine compared to oxygen.
Step 3: Detailed Explanation:
1. Fluorine is a monovalent halogen and can only form a single covalent bond (sigma bond) with the central manganese atom. To reach an oxidation state of $+7$ solely with fluorine, Mn would theoretically need to be surrounded by 7 bulky fluorine atoms ($MnF_7$), which creates impossible steric hindrance and repulsion, making such a molecule highly unstable.

2. Oxygen, being divalent, has the ability to form multiple bonds (double bonds utilizing $p\pi-d\pi$ interactions). This allows oxygen to stabilize the highest oxidation state of Mn ($+7$ in $Mn_{2}O_{7}$ or $MnO_{4}^{-}$) using significantly fewer coordinating atoms. Only 4 oxygen atoms are needed to reach the valence requirements, vastly reducing steric crowding.
Step 4: Final Answer:
The ability of oxygen to form double bonds is the primary reason it can stabilize higher oxidation states than fluorine.
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