The energy of one mole of photons of radiation of frequency 2 \(\times\)1012 Hz in Jmol-1 is ________ (Nearest integer)
[Given : \(h=6.626\times10^{-34}Js\)
\(N_{A}=6.022\times10^{23}mol^{-1}\)]
To calculate the energy of one mole of photons, first determine the energy of a single photon using E = hν. Then, multiply this by Avogadro’s number (NA) to find the energy for one mole.
To determine the energy of one mole of photons with a frequency of \(2 \times 10^{12} \, \text{Hz}\), use the formula for energy \(E\) of a photon:
\[ E = h \times \nu \]
where \(h\) is Planck's constant \((6.626 \times 10^{-34} \, \text{Js})\) and \(\nu\) is the frequency \((2 \times 10^{12} \, \text{Hz})\).
Substitute the given values into the equation:
\[ E = 6.626 \times 10^{-34} \, \text{Js} \times 2 \times 10^{12} \, \text{Hz} \]
Calculate:
\[ E = 1.3252 \times 10^{-21} \, \text{J per photon} \]
The energy for one mole of photons is found by multiplying the energy per photon by Avogadro's number \(N_A = 6.022 \times 10^{23} \, \text{mol}^{-1}\):
\[ E_{\text{mole}} = 1.3252 \times 10^{-21} \, \text{J/photon} \times 6.022 \times 10^{23} \, \text{photon/mol} \]
Perform the multiplication:
\[ E_{\text{mole}} = 797.52 \, \text{J/mol} \]
Rounding to the nearest integer, the energy is \(798 \, \text{J/mol}\).
Thus, the final energy of one mole of photons is 798 J/mol, which falls within the expected range of 798 to 798.
Given below are two statements:
Statement (I) : The dimensions of Planck’s constant and angular momentum are same.
Statement (II) : In Bohr’s model, electron revolves around the nucleus in those orbits for which angular momentum is an integral multiple of Planck’s constant.
In the light of the above statements, choose the most appropriate answer from the options given below: