The energy of one mole of photons of radiation of frequency 2 \(\times\)1012 Hz in Jmol-1 is ________ (Nearest integer)
[Given : \(h=6.626\times10^{-34}Js\)
\(N_{A}=6.022\times10^{23}mol^{-1}\)]
To calculate the energy of one mole of photons, first determine the energy of a single photon using E = hν. Then, multiply this by Avogadro’s number (NA) to find the energy for one mole.
To determine the energy of one mole of photons with a frequency of \(2 \times 10^{12} \, \text{Hz}\), use the formula for energy \(E\) of a photon:
\[ E = h \times \nu \]
where \(h\) is Planck's constant \((6.626 \times 10^{-34} \, \text{Js})\) and \(\nu\) is the frequency \((2 \times 10^{12} \, \text{Hz})\).
Substitute the given values into the equation:
\[ E = 6.626 \times 10^{-34} \, \text{Js} \times 2 \times 10^{12} \, \text{Hz} \]
Calculate:
\[ E = 1.3252 \times 10^{-21} \, \text{J per photon} \]
The energy for one mole of photons is found by multiplying the energy per photon by Avogadro's number \(N_A = 6.022 \times 10^{23} \, \text{mol}^{-1}\):
\[ E_{\text{mole}} = 1.3252 \times 10^{-21} \, \text{J/photon} \times 6.022 \times 10^{23} \, \text{photon/mol} \]
Perform the multiplication:
\[ E_{\text{mole}} = 797.52 \, \text{J/mol} \]
Rounding to the nearest integer, the energy is \(798 \, \text{J/mol}\).
Thus, the final energy of one mole of photons is 798 J/mol, which falls within the expected range of 798 to 798.
| List I (Spectral Lines of Hydrogen for transitions from) | List II (Wavelength (nm)) | ||
| A. | n2 = 3 to n1 = 2 | I. | 410.2 |
| B. | n2 = 4 to n1 = 2 | II. | 434.1 |
| C. | n2 = 5 to n1 = 2 | III. | 656.3 |
| D. | n2 = 6 to n1 = 2 | IV. | 486.1 |