- Manganese (Mn) exhibits a lower melting point than Iron (Fe) attributed to its lower atomic number and less stable crystal structure.
- Technetium (Tc) has a lower melting point than Ruthenium (Ru) owing to disparities in atomic structure and bonding.
- Rhenium (Re) has a lower melting point than Osmium (Os) because Os possesses a higher atomic number and exhibits stronger metallic bonding, resulting in a superior melting point. Consequently, the correct ordering is \( {Mn}<{Fe}, \ {Tc}<{Ru} \ {and} \ {Re}<{Os} \).