Step 1: Identify the substance. Gunpowder, or black powder, is the first known chemical explosive.
Step 2: Recall its composition. It has three main ingredients:
Potassium nitrate (\(KNO_3\)): The oxidizer.
Charcoal (Carbon): The fuel.
Sulphur: A secondary fuel and stabilizer, lowering the ignition temperature.
Step 3: Check the proportions. Black powder's standard optimal composition is about 75% potassium nitrate, 15% charcoal, and 10% sulfur by weight. Option (1) has similar proportions (with swapped sulfur and charcoal percentages, a common change). Options (2) and (4) describe smokeless powders like cordite, not gunpowder. Option (3) is an incorrect mixture.