The given question asks for the monomer of Novolac. Novolac is one of the most common types of phenolic resins, which are important synthetic polymers. To determine the correct monomer, we must understand how Novolac is formed.
The polymerization process of Novolac involves the condensation reaction between phenol and formaldehyde under acidic conditions. The initial product of this reaction is ortho- and para-Hydroxymethylphenols, which further polymerize to form Novolac.
Let's evaluate the given options:
Based on these evaluations, the correct answer is o-Hydroxymethylphenol, as it directly relates to the formation of Novolac through the polymerization of phenol with formaldehyde.