| Column-I | Column-II |
| (A) Zone refining | (P) pig iron |
| (B) Electrolysis | (Q) Al |
| (C) Reverberatory furnace | (R) Si |
| (D) Blast furnace | (S) Cu |
A-R, B-Q, C-S, D-P
A-Q, B-P, C-S, D-R
A-P, B-S, C-Q, D-R
A-S, B-P, C-R, D-Q
To solve this question, we need to understand the purpose and use of each method mentioned in Column-I, and with which material or element they are typically associated, as given in Column-II.
Based on the above analysis, the correct matching between Column-I and Column-II is: A-R, B-Q, C-S, D-P.
| Column-I | Column-II |
| Zone refining | Si (R) |
| Electrolysis | Al (Q) |
| Reverberatory furnace | Cu (S) |
| Blast furnace | pig iron (P) |
Thus, the correct option is A-R, B-Q, C-S, D-P.