Step 1: Understanding the Concept:
Vitamins are micronutrients required for specific biochemical functions. Lack of these leads to characteristic deficiency syndromes.
Step 2: Detailed Explanation:
A. Vitamin B12: Essential for RBC maturation. Deficiency leads to Pernicious anaemia. (A $\to$ IV).
B. Vitamin D: Essential for Calcium absorption. Deficiency causes Rickets in children. (B $\to$ III).
C. Vitamin B2 (Riboflavin): Deficiency causes inflammation at the corners of the mouth called Cheilosis. (C $\to$ I).
D. Vitamin B6 (Pyridoxine): Involved in amino acid metabolism. Deficiency can lead to Convulsions. (D $\to$ II).
Step 3: Final Answer:
The match A-IV, B-III, C-I, D-II corresponds to option (D).