Step 1: Understand the setup using right-triangle trigonometry instead of the altitude formula.
Since $A\left(0, \frac{5\sqrt{3}}{2}\right)$ and $D(0,0)$ both have $x = 0$, the segment $AD$ lies along the y-axis, and $D$ is the midpoint of $BC$. Because triangle $ABC$ is equilateral and $AD$ is the median from $A$, $AD$ is also perpendicular to $BC$, so $BC$ lies along the x-axis and angle $ADB = 90^{\circ}$.
Step 2: Find the length AD.
Using the distance formula between $A\left(0, \frac{5\sqrt{3}}{2}\right)$ and $D(0,0)$:
\[ AD = \sqrt{(0-0)^2 + \left(\frac{5\sqrt{3}}{2} - 0\right)^2} = \frac{5\sqrt{3}}{2} \]
Step 3: Use the base angle of the equilateral triangle in right triangle ABD.
In an equilateral triangle every interior angle is $60^{\circ}$, so angle $ABD = 60^{\circ}$. Triangle $ABD$ is right angled at $D$ (since $AD \perp BC$). In this right triangle, $AD$ is the side opposite angle $B$, and $BD$ is the side adjacent to angle $B$. So we can write the tangent ratio:
\[ \tan(\angle ABD) = \frac{AD}{BD} \]
\[ \tan 60^{\circ} = \frac{AD}{BD} \]
Step 4: Solve for BD.
We know $\tan 60^{\circ} = \sqrt{3}$, so
\[ \sqrt{3} = \frac{\frac{5\sqrt{3}}{2}}{BD} \]
\[ BD = \frac{\frac{5\sqrt{3}}{2}}{\sqrt{3}} = \frac{5}{2} \]
Step 5: Locate B and C using symmetry.
Since $D(0,0)$ is the midpoint of $BC$ and $BC$ lies on the x-axis, $B$ and $C$ are at equal distances of $\frac{5}{2}$ from $D$, on opposite sides. So
\[ B = \left(-\frac{5}{2}, 0\right), \quad C = \left(\frac{5}{2}, 0\right) \]
Final Answer:
The coordinates of B and C are $\left(-\frac{5}{2}, 0\right)$ and $\left(\frac{5}{2}, 0\right)$, so option (B) is correct.
\[ \boxed{\left(-\tfrac{5}{2}, 0\right), \left(\tfrac{5}{2}, 0\right)} \]