In the formation of photochemical smog, two oxides of nitrogen are significantly formed. The oxidation states of nitrogen in these oxides are respectively
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The chief nitrogen oxides responsible for photochemical smog are
\[
\boxed{\mathrm{NO}\;(N=+2)}
\]
and
\[
\boxed{\mathrm{NO_2}\;(N=+4).}
\]