Question:medium

In an ideal gas at temperature $T$, the average force that a molecule applies on the walls of a closed container depends on $T$ as $T^q$. A good estimate for $q$ is :

Updated On: Apr 1, 2026
  • $2$
  • $1$
  • $\frac{1}{2}$
  • $\frac{1}{4}$
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The Correct Option is B

Solution and Explanation

To determine the relationship between the average force that a molecule applies on the walls of a closed container and the temperature \( T \), let's analyze the behavior of an ideal gas. 

According to the kinetic theory of gases, the pressure \( P \) exerted by an ideal gas is given by:

\(P = \frac{1}{3} N m \overline{v^2} / V\)

where:

  • \( N \) is the number of molecules,
  • \( m \) is the mass of each molecule,
  • \( \overline{v^2} \) is the mean square velocity of the molecules,
  • \( V \) is the volume of the container.

The mean square velocity \( \overline{v^2} \) is related to the temperature by:

\(\overline{v^2} = \frac{3kT}{m}\)

where:

  • \( k \) is the Boltzmann constant,
  • \( T \) is the absolute temperature.

Substituting \( \overline{v^2} \) in the equation for pressure:

\(P = \frac{1}{3} N \frac{3kT}{V} = \frac{NkT}{V}\)

The average force (\( F \)) exerted by a molecule on the walls is related to the pressure by:

\(F = PA\)

Here, \( A \) is the area of the wall. Since we consider molecular impacts, we can relate force per collision and frequency of collisions, showing how force is proportional to pressure.

From kinetic theory: \(P \propto T\).

Thus, the force is \(F \propto T \), and hence\)

Therefore, the correct estimate for \( q \) is 1, meaning that the average force exerted by a gas molecule depends linearly on the temperature \( T \).

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