Step 1: In single-slit diffraction, the \( m \)-th diffraction minimum occurs when:
\[ a \sin \theta_m = m\lambda, \]
where \( a \) is the slit width, \( \lambda \) is the light wavelength, and \( m \) is the order.
Step 2: When the 2nd order minimum of \( \lambda_1 \) and the 3rd order minimum of \( \lambda_2 \) coincide, we equate the angles:
\[ 2\lambda_1 = 3\lambda_2 \]
Therefore:
\[ \frac{\lambda_1}{\lambda_2} = \frac{3}{2}. \]