To find the value of \( r \) at which the probability \( P(X = r) \) is maximum for a binomial distribution, we need to use the formula for the mode of a binomial distribution. For a binomial distribution with parameters \( n \) and \( p \), where \( X \sim B(n, p) \), the mode is generally located at:
In this specific problem, the parameters are given as \( n = 100 \) and \( p = \frac{1}{3} \).
Let's compute:
Thus, the mode of the distribution, or where \( P(X = r) \) is maximum, occurs at \( r = 33 \).
Let's evaluate the options:
Thus, the correct answer is 33.