Question:hard

If dichloromethane (DCM) and water ${(H_2O)}$ are used for differential extraction, which one of the following statements is correct ?

Updated On: Apr 2, 2026
  • DCM and ${(H_2O)}$ would stay as lower and upper layer respectively in the S.F.
  • DCM and ${(H_2O)}$ will be miscible clearly
  • DCM and ${(H_2O)}$ would stay as upper and lower layer respectively in the separating funnel (S.F.)
  • DCM and ${(H_2O)}$ will make trubid/colloidal mixture
Show Solution

The Correct Option is A

Solution and Explanation

To solve this question, we need to understand the solubility and density properties of dichloromethane (DCM) and water (${H_2O}) when used in a differential extraction process in a separating funnel (S.F.).

  1. Miscibility: DCM and water are immiscible liquids. This means they do not dissolve in each other and will thus form separate layers when mixed.
  2. Density Consideration: The density of a liquid determines its position in a layer when two immiscible liquids are placed in a container.
    • The density of water is approximately 1 \, \text{g/cm}^3.
    • The density of DCM is approximately 1.33 \, \text{g/cm}^3.
    Since DCM is denser than water, it will form the lower layer.
  3. Conclusion: Based on their densities, dichloromethane (DCM) will form the lower layer while water (${H_2O}) will form the upper layer in a separating funnel.

Therefore, the correct statement is: DCM and ${H_2O} would stay as lower and upper layer respectively in the S.F.

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