Step 1: Understand the question.
We need two molecules: one ring with 2 nitrogen atoms and one ring with 5 nitrogen atoms. These are nitrogenous bases, so we recall how many nitrogen atoms each base has.
Step 2: Sort bases into two families.
Pyrimidines (cytosine, thymine, uracil) have a single ring with 2 nitrogen atoms. Purines (adenine, guanine) have a double ring with more nitrogen atoms.
Step 3: Find the base with 2 nitrogen atoms.
Among the pyrimidines, cytosine has 2 nitrogen atoms in its single ring. So the first molecule should be cytosine.
Step 4: Find the base with 5 nitrogen atoms.
Among the purines, adenine has 5 nitrogen atoms (4 in its double ring plus one amino nitrogen). So the second molecule should be adenine.
Step 5: Match with the options.
We need the pair cytosine then adenine. Only one option gives this pairing.
Step 6: Final answer.
The pair is Cytosine and Adenine.
\[ \boxed{\text{Cytosine, Adenine}} \]